Programmatically printing WebBrowser and setting its PrinterSettings in VB - vb.net

Question

I am trying to find a way to set PrinterSettings when printing contents of WebBrowser similar to the following code
Dim doc As PrintDocument = New PrintDocument()
With doc
.PrinterSettings = New PrinterSettings()
With .PrinterSettings
.PrinterName = "PrinterName"
.PrintToFile = True
.PrintFileName = Path.Combine(AppDomain.CurrentDomain.BaseDirectory + "test.pdf")
End With
End With
doc.Print()
I converted this from a C# code I've found that tells how to set PrinterSettings programmatically.
Is there a way to combine the code above with WebBrowser.Print() in order to print HTML and set PrinterSettings programmatically
I have tried doing it like this thinking that this code might set default printer to Microsoft Print to PDF
Dim doc As PrintDocument = New PrintDocument()
With doc
.PrinterSettings = New PrinterSettings()
With .PrinterSettings
.PrinterName = "Microsoft Print to PDF"
.PrintToFile = True
.PrintFileName = Path.Combine(AppDomain.CurrentDomain.BaseDirectory + "test.pdf")
End With
End With
WebBrowser.Print()
But it prints on the default printer and not on Microsoft Print to PDF
Edit: The WebBrowser contains the document I'm trying to print in HTML Format and some inline CSS. The WebBrowser don't have a UI, It is a plain code Declared as Private WithEvents WebBrowser As WebBrowser. Hope this helps clear my problem, thanks.
Edit(2): Setting the Default Printer have been problematic to me because of the printer setting "let windows manage my printers." Unchecking this allow the application to set the default printer. credits to K J

Answer 1

Try This :
Vote for me if I've helped you.
Dim doc As New PrintDocument()
With doc
With .PrinterSettings
.PrinterName = "PrinterName" ' exam: Fax
.PrintToFile = True
.PrintFileName = "The location of the file you want to print with the formula" ' exam -> C:\CV.pdf
End With
End With
doc.Print()